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PTFE Performance
Release time:
2023-09-25 14:46
Weather resistance
Polytetrafluoroethylene has extremely high chemical corrosion resistance, such as in concentrated sulfuric acid, nitric acid, hydrochloric acid, and even boiled in aqua regia, its weight and performance are unchanged, and it is almost insoluble in most solvents. Slightly soluble in all alkanes (about 0.1g/100g) above 300°C. PTFE does not absorb moisture, non-flammable, oxygen, ultraviolet are extremely stable, so it has excellent weather resistance.
It is worth noting that PTFE cannot withstand a very strong reducing atmosphere
Molten alkali metal, ammonia alkali solution (alkali metal dissolved in liquid ammonia), some fluoride (such as TFA), naphthalene sodium salt, etc. can quickly corrode PTFE products
electrical properties
PTFE has low dielectric constant and dielectric loss over a wide frequency range, and high breakdown voltage, volume resistivity and arc resistance.
Radiation resistance
The radiation resistance of PTFE is poor (104 rad), and the degradation caused by high-energy radiation, the electrical and mechanical properties of the polymer are significantly reduced.
Aggregation
Polytetrafluoroethylene is produced by radical polymerization of tetrafluoroethylene. Industrial polymerization is carried out with stirring in the presence of a large amount of water to disperse the heat of reaction and to facilitate temperature control. The polymerization is generally carried out at a temperature of 40 to 80 ° C. under a pressure of 3 to 26 kgf/cm2, and an inorganic persulfate, an organic peroxide, or a redox initiating system can be used as an initiator. The exotherm was 171.38kJ per mole of tetrafluoroethylene polymerized. The dispersion polymerization requires addition of a perfluoro-type surfactant such as perfluorooctanoic acid or a salt thereof.
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Polytetrafluoroethylene is called "plastic king". Roy Planct, the father of fluororesin, began to study freon substitutes in DuPont Company in the United States in 1936. They collected some tetrafluoroethylene and stored it in steel cylinders for the next experiment. However, when the pressure reducing valve of the steel cylinder was opened the next day, no gas overflowed. They thought it was air leakage, but when the steel cylinder was weighed, they found that the steel cylinder did not lose weight. They sawed through the cylinder and found a large amount of white powder, which was Teflon.
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PTFE film is made of molded sintered cylindrical blanks, which are cut into films by machine tools and then calendered. According to the different treatment methods, it can be divided into three kinds of oriented film, semi-oriented film and non-oriented film. At present, PTFE film products include porous film, microfiltration membrane, color film and so on.
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